Vulpix @ Heat Rock  
Ability: Drought  
Level: 5  
EVs: 52 HP / 196 Def / 236 Spe  
Timid Nature  
- Overheat  
- Energy Ball  
- Weather Ball  
- Hypnosis
Set Details: This set is exclusively used on sun teams. The Defense EVs allows Vulpix to survive a Life Orb Earthquake from Diglett

Vulpix @ Choice Scarf 
Ability: Drought  
Level: 5  
EVs: 52 HP / 196 SpA / 236 Spe  
Timid Nature  
- Overheat  
- Energy Ball  
- Weather Ball  
- Hypnosis